Polymer

 
 
9.3  Polymer
 

1. Polymer is a large molecule formed by chains of monomer

2. There are 2 types of polymers

  • natural polymers
  • synthetic polymers

3. Natural polymers: polymers that exist naturally

 
Natural polymer Monomer Use
Starch Glucose
  • Produces energy
Protein Amino acid
  • Build cells and body tissues
Natural rubber Isoprene
  • To make rubber-based products
 
4. Synthethic polymers: man-made polymers using chemical susbtances
 
Synthetic polymer Monomer Use
Polythene Ethene
  • To make plastic bottles, plastic bags and pails
Polystyrene Styrene
  • To make packing container for electrical equipment
Perspex Methyl methacrylate
  • To make aeroplane mirrors, windows for vehicles
Synthetic rubber Neoprene
  • To make gloves, tyres and shoe soles
 

5. Polymerisation: the process of joining the monomers through the formation of chemical bonds to produce a long-chain polymer

6. Depolymerisation: the process of splitting a long chain polymer into its monomer through chemical reactions

7. Addition polymerisation: polymerisation that involves a monomer of the same type by breaking a double bond into a single bond

8. Natural rubber

  • In latex, rubber molecules in the form of chains are covered with a layer of protein membrane
  • Negative charges surround the outer surface of the membrane
  • This causes the rubber molecules to repel each other

9. The action of acid on latex

  • An acid is added to the latex
  • Positively charges hydrogen ions from the acid will neutralise the negative charges on the surface of the protein membrane
  • Rubber molecules will collide with one another
  • This will break the protein membrane and the chaine of the rubber polymer
  • It coagulate to form solid lumps

* Bateria from air will also produces acid that neutralises the protein membranes of rubber molecules

10. The action of alkali on latex

  • Alkali is added to the latex
  • Negative charges hydroxide ions from the alkali will neutralise the hydrogen ions from the acid
  • Negative charges remian on the protein membrane
  • Rubber molecules will remain in liquid form

11. Vulcanisation of rubber 

  • Vulcanisation is a process of heating rubber with sulphur
  • It improves the properties of rubber and make it stronger
  • Rubber obtained throught the process is known as vulcanised rubber

12. Properties of vulcanised rubber

  • Hard
  • More elastic
  • Good electrical insulator
  • Difficult to be oxidised in air
  • Does not react with acid and alkali
  • Not permeable to liquid and air
  • Resistant to heat

13. Uses of vulcanised rubber

  • Tyres of vehicles
  • Rubber gloves
  • Shoe soles