Polymer

 

Definition of polymer
A long chain molecule that is made from a combination of many repeating basic units
 
  • There are various items around us that are made up of polymers such as protein, starch, polyethylene and nylon.
  • The basic unit of a polymer is called a monomer.
  • The reaction of monomer fusion to produce a polymer is called the polymerisation reaction.
  • Polymers can be classified into several groups based on the source of the polymer, the way the polymer is produced and the characteristics of the resulting polymer.
 

Polymer Sources

 
  • Polymers consist of natural polymers or synthetic polymers.
  • Natural polymers are polymers that are produced naturally and can be obtained from the environment.
  • Examples of natural polymers include starch, protein and cotton.
  • Synthetic polymers are produced by humans through chemical reactions in laboratories or in factories.
  • Nylon, polyethylene, polystyrene and polyvinyl chloride (PVC) are among the examples of synthetic polymers produced in the industrial sector.
  • Starch is a natural polymer made from glucose.
  • Meat is one of the sources of protein. Proteins are made from amino acids that are a type of monomer.
 
Polymer Sources Polymer Monomer
Natural Starch Glucose
Natural Cellulose Glucose
Natural Protein Amino Acids
Natural Natural Rubber Isoprene
Synthetic Polystyrene Styrene
Synthetic Polypropene Propene
Synthetic Polyvinyl Chloride Vinyl Chloride
 

Types of Polymers

 
Type of polymer Characteristics

Thermoplastic polymers

  • Can be molded repeatedly after being heated and can be recycled.
  • When heated, the thermoplastic polymer melts and hardens when cooled.
  • Examples: Polyethane, polyvinyl chloride (PVC), nylon.

Thermosetting polymers

  • Cannot be remoulded after heating.
  • Normally disintegrate or burn upon heating and cannot be recycled.
  • Example: melamine, bakelite.

Elastomer polymers

  • Can be stretched and can return to their original shape when released.
  • Possess high elasticity properties.
  • Example: polyurethane, styrene-butadiene rubber (SBR).
 

Polymerisation Reactions

 
  • Polymerisation reactions are divided into two types, namely addition polymerisation and condensation polymerisation.
  • Addition polymerisation occurs when the monomer has a double covalent bond between the carbons, C = C reacting with each other.
 
Addition polymerisation
 
Monomer Polymer
Ethene Polyethane
Propene Polypropene
Chloroethene (vinyl chloride) Polychloretene (Polyvinyl chloride, PVC)
Styrene Polystyrene

 

Polymer Characteristics
Polyethane Durable and strong
Polypropene Durable
Polyvinyl chloride, PVC Strong and hard
Polystyrene Lightweight and heat insulator

 

Polymer Uses
Polyethane Plastic bags, bottles plastic and plastic wrapper
Polypropene Toys and textiles
Polyvinyl chloride, PVC Water pipes and electrical insulation
Polystyrene Heat insulator and wrappers food
 
  • During the reaction, double bonds are "opened" and monomers are "added" to the molecular chain to produce a polymer.
  • The following diagram shows the polymerisation of ethene to produce polyethene.
 
Addition polymerisation of ethene
 
Condensation Polymerisation
 
  • Condensation polymerisation involves at least two different types of monomers.
  • The monomers involved have two functional groups involved in the polymerization reaction.
  • The result of condensation polymerization is a polymer and another product such as water or HCl molecules.
 
Condensation polymerisation reaction to produce terylene

 

Condensation polymerisation reaction to produce nylon
 

Use of Polymers in Everyday Life

 
  • Features not found in natural polymers include:
 
Characteristics of Synthetic Polymers
Good thermal insulation
Light, strong and hard
Inert and not reactive
High heat resistance
 

Uses of Synthetic Polymers

 
  • Various medical and laboratory devices are made from polypropene.
  • The most widespread use of polyethylene is as a plastic bag.
  • Nylon produces yarn that is important for the textile industry.
  • Acrylic polymer coatings are used to produce waterproof roofs.
 

Polymers and the Environment

 
  • The nature of some polymers which are durable and take a very long time to decompose causes serious pollution problems.
  • Pollution in the oceans causes many living things to die and microplastics to enter the food chain.
  • Garbage disposal centers are filled with non-biodegradable plastic bags that will affect the environment.
  • Recycling is the easiest way for consumers to ensure synthetic polymers do not end up in landfills.
  • The introduction of degradable or decomposable polymers especially for plastic products allows pollution to be reduced.
  • Additives are included to allow plastic items to decompose naturally by bacteria (biodegradation) or decompose by light (photodegradation).
  • Plastic items will decompose faster and can reduce the problem of dumping plastic items at landfills as well as safer for wild animals.