Thermal Equilibrium

4.1

 Thermal Equilibrium

 
 
  • When two objects come into contact, heat will be transferred
  • Net heat moves from hotter objects to cooler objects
  • The temperature of the cold object increases, the temperature of hot objects is reduced
  • When the temperature of the objects is the same, heat transfer is equal and net heat transfer is zero
  • Object has reached thermal equilibrium
 
 
Conditions for thermal equilibrium
  • Same temperature
  • Same rate of heat flow
  • Net heat flow zero
 

Mercury thermometer

The benefits of using mercury:

  • High boiling point
  • Low melting point
  • Good heat conductor
  • Expands and contracts uniformly
  • Opaque (easily visible)
  • Cohesive forces high (non-stick to wall)
 

How to increase the sensitivity of a mercury thermometer

  • Reduce the thickness of the glass bulb
    • Heat transfer between the mercury and environment faster
  • Reduce the thickness of the glass bulb
    • Absorbs heat from the environment with higher rates
  • Use small diameter capillary tubes
    • Mercury rise higher when the diameter of the tube decreases
  • Reduce the thickness of the glass tube
    • Heat transfer between the mercury and environment faster
 

 Thermometer calibration

  1. To calibrate a thermometer means to put the correct mark of reading at the correct place so that other temperature can be deduced from these marks. 
  2. To do this, two extreme points are chosen to mark its scale and these points must be able to be reproduced accurately.

  3. Usually, we take the steam point of pure water as \(100\;^0\text{C}\) and the ice point of water as \(0\;^0\text{C}\).
 
  Calculation for non-calibrated thermometer  
  \(\theta=\dfrac{l_\theta-l_0}{l_{100}-l_0}\times100\;^0\text{C}\)

 where \(\theta\) = temperature, \(l_0\) = length when temperature is \(0\;^0\text{C}\)\(l_{100}\) = length when temperature \(100\;^0\text{C}\)