Chemistry Chapter 4: Polymer
4.3 Synthetic Rubber
Synthetic Rubber | Chemistry Form 5
CHEMISTRY • Form 5 • Chapter 4: Polymer

4.3Synthetic Rubber

Synthetic rubber is an artificial elastomer polymer largely produced as by-products of petroleum. Invented in the early 20th century to replace natural rubber, synthetic rubber now accounts for more than 60% of manufactured rubber products worldwide due to its superior resistance to heat, chemicals, and oxidation.

Learning Objectives

  • Explain what synthetic rubber is.
  • List the key characteristics of synthetic rubber.
  • Identify examples of synthetic rubber along with their specific properties and uses.
  • Justify the use of natural rubber and synthetic rubber based on their characteristics.
  • Describe the environmental impacts of synthetic rubber disposal and methods to overcome rubber waste.

Characteristics and Examples of Synthetic Rubber

Six general properties and common synthetic rubber types with their applications.

Characteristics and examples of synthetic rubber

Brief Explanation

Definition, origin, characteristics and comparison of synthetic rubber.

Synthetic rubber is a synthetic polymer that is elastic in nature or an elastomer polymer. Most synthetic rubber is produced as by-products of petroleum.

Definition and Origin

Synthetic rubber was invented in the early 20th century to replace natural rubber. Currently, more than 60% of rubber products are manufactured using synthetic rubber.

Industrial Advantage

Mass production capacity and lack of reliance on weather conditions or tree diseases make synthetic rubber the primary choice for manufacturing industries.

Characteristics of Synthetic Rubber

  • Hard
  • Elastic
  • Resistant to heat
  • Heat insulator
  • Resistant to oxidation
  • Resistant to chemicals

Natural Rubber vs Synthetic Rubber

Natural rubber takes a short time to decompose biologically, but is less resistant to heat and chemical solvents.

Synthetic rubber lasts longer and is highly resistant to heat, oxidation and chemicals, but takes a very long time to decompose naturally.

Synthetic Rubber Characteristics Uses
Neoprene (polychloroprene) High heat resistance, oxidation resistance, and flame resistance. Conveyor belts, petrol rubber hoses, and gloves.
Styrene-butadiene rubber (SBR) Abrasion resistance and high heat resistance. Tyres and shoe soles.
Silicone rubber High temperature resistance and inert. Medical implants, cooking utensils, automotive components, and sealants.
Thiokol Oil and solvent resistance. Sealants.
Nitrile rubber Oil and solvent resistance. Gloves.

Try to Answer First

Answer mentally, then check the explanation.

1

What is meant by synthetic rubber?

Answer: Synthetic rubber is a synthetic polymer that is elastic in nature or an elastomer polymer.
2

Surgical gloves can be manufactured by using natural rubber or synthetic rubber. Name one synthetic rubber that can be used to manufacture gloves, and state how its characteristics differ from natural rubber gloves.

Answer: Nitrile rubber (or neoprene). Synthetic rubber gloves are more resistant to chemicals, oils, and solvents compared to natural rubber gloves, and they do not degrade as easily when exposed to chemicals.
3

Why is synthetic rubber widely used in manufacturing vehicle tyres instead of natural rubber alone?

Answer: Synthetic rubber, such as styrene-butadiene rubber (SBR), possesses higher abrasion resistance and superior heat resistance compared to natural rubber, allowing tyres to withstand intense road friction without wearing out rapidly.

Common Mistakes

Avoid these errors when learning about synthetic rubber.

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Confusing the specific properties of different synthetic rubbers, for example mistaking SBR as oil-resistant instead of Nitrile rubber or Thiokol.
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Assuming synthetic rubber is biodegradable like natural rubber; synthetic rubber takes an extremely long time to decompose naturally.
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Stating that synthetic rubber is harvested from trees; it is synthesised primarily from petroleum by-products.

Concept Misunderstandings

Compare each misconception with the correct fact.

Misconception

Synthetic rubber is completely rigid and cannot stretch like natural rubber.

Correct Fact

Synthetic rubber is an elastomer, meaning it is inherently elastic and can stretch and return to its original shape, while also being harder and more chemically resistant than natural rubber.

Misconception

Natural rubber is superior in all aspects because it comes from a natural source.

Correct Fact

Natural rubber easily deteriorates when exposed to heat, oxygen, and chemical solvents, making synthetic rubber preferable for industrial uses like petrol hoses, engine sealants, and vehicle tyres.

Summary

Key facts to remember.

  • Synthetic rubber is an elastic polymer (elastomer) derived from petroleum by-products.
  • Key characteristics include being hard, elastic, a heat insulator, and resistant to heat, oxidation, and chemicals.
  • Common examples include Neoprene (petrol hoses, conveyor belts), SBR (tyres, shoe soles), Silicone rubber (medical implants, cooking utensils), Thiokol (sealants), and Nitrile rubber (gloves).
  • While synthetic rubber provides long durability and mass-production stability, its non-biodegradable nature causes environmental waste issues, prompting recycling efforts and the development of greener alternatives like Ekoprena and Pureprena.

Short Activity

Complete all parts before checking your score.

A. Objective Quiz

1

Which type of synthetic rubber is most suitable for making vehicle tyres due to its high abrasion resistance?

2

What is a major environmental disadvantage of synthetic rubber compared to natural rubber?

B. Fill in the Blanks

3

Synthetic rubber is a synthetic polymer that is elastic in nature or an ________ polymer.

4

Most synthetic rubber is produced as by-products of ________.

C. Match the Synthetic Rubber with Its Characteristic or Use

Drag each synthetic rubber on desktop. On mobile, tap a rubber and then tap the matching box.

Synthetic Rubber

Neoprene Silicone rubber Nitrile rubber Thiokol

Characteristic / Use

1High flame and oxidation resistance; used for petrol rubber hoses and conveyor belts.
2Inert with high temperature resistance; used for medical implants and cooking utensils.
3Resistant to oils and solvents; commonly manufactured into gloves.
4High resistance to oils and solvents; primarily used for sealants.
Complete every answer before checking.
 

Keywords

Tap or hover over a term to read its meaning.

Synthetic rubber Elastomer Styrene-butadiene rubber (SBR) Neoprene Silicone rubber Nitrile rubber Thiokol Ekoprena and Pureprena